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For organic and natural wines in the province of Grosseto, first look around Campagnatico, de Poggio Murella and the hills around Grosseto. For natural wine in the strict sense, I Nove Filari, in Campagnatico, announces spontaneous fermentations and no added sulfites; contact them before going to check the tasting options. Near the hot springs of Saturnia, Ranchelle works with local grape varieties organically and biodynamically, with low-intervention winemaking. Visits are by appointment.
If you're mainly looking for certified organic, Podere La Pace, in the Massa Marittima area, offers a visit and tasting: allow about 60 minutes and €15, or 90 minutes and €30 for the option with more wines and a snack. Book in advance; the posted sales hours apply to the summer period. At Purovino, in the Grosseto countryside, the wines are presented as low in sulfites: cellar tasting by reservation all year round, brunch on the terrace fromApril to November.
A useful point: "organic" concerns how the vines are grown, while "natural" does not guarantee a single method. If you want to avoid added sulfites, ask explicitly before booking or buying; practices can vary from one cuvée to another. The estates are scattered, so plan for a car and check the time slots directly with the winery.
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